许振岚, 徐艺, 张昌朋, 汤涛, 张春荣, 俞建忠, 赵华, 赵学平. 环酰菌胺在土壤中的吸附及降解特性[J]. 农药学学报, 2020, 22(1): 188-192. DOI: 10.16801/j.issn.1008-7303.2020.0008
    引用本文: 许振岚, 徐艺, 张昌朋, 汤涛, 张春荣, 俞建忠, 赵华, 赵学平. 环酰菌胺在土壤中的吸附及降解特性[J]. 农药学学报, 2020, 22(1): 188-192. DOI: 10.16801/j.issn.1008-7303.2020.0008
    XU Zhenlan, XU Yi, ZHANG Changpeng, TANG Tao, ZHANG Chunrong, YU Jianzhong, ZHAO Hua, ZHAO Xueping. Investigation on adsorption and degradation of fenhexamid in soil[J]. Chinese Journal of Pesticide Science, 2020, 22(1): 188-192. DOI: 10.16801/j.issn.1008-7303.2020.0008
    Citation: XU Zhenlan, XU Yi, ZHANG Changpeng, TANG Tao, ZHANG Chunrong, YU Jianzhong, ZHAO Hua, ZHAO Xueping. Investigation on adsorption and degradation of fenhexamid in soil[J]. Chinese Journal of Pesticide Science, 2020, 22(1): 188-192. DOI: 10.16801/j.issn.1008-7303.2020.0008

    环酰菌胺在土壤中的吸附及降解特性

    Investigation on adsorption and degradation of fenhexamid in soil

    • 摘要: 为评价环酰菌胺在土壤中的生态风险,采用超高效液相色谱-串联质谱 (UPLC-MS/MS) 方法测定了土壤和水中环酰菌胺的残留量,研究了该农药在红壤和水稻土中的吸附及降解特性,并对其淋溶特性进行了分析,评估了该农药对地下水的污染风险。结果表明:环酰菌胺在红壤和水稻土中的吸附符合Freundlich吸附等温线方程,KOC 值分别为373.69 和726.86 mL/g,水稻土对环酰菌胺的吸附能力强于红壤。好氧条件下,环酰菌胺在红壤和水稻土中的降解半衰期分别为0.63和5.06 d,积水厌氧条件下的降解半衰期分别为6.80和9.24 d,表明环酰菌胺在好氧条件下降解较快。环酰菌胺在红壤和水稻土中的地下水污染指数 (groundwater ubiquity score) 分别为1.19和1.10,表明其对地下水的污染风险较低。结果可为环酰菌胺的生态风险评估提供参考。

       

      Abstract: In order to evaluate the ecological risk of fenhexamid in soil, the adsorption and degradation of fenhexamid in red soil and paddy soil were investigated. The leaching properties and the potential of ground water contamination were evaluated. The residues of fenhexamid were measured by ultrahigh performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). The adsorption of fenhexamid in red soil and paddy soil followed the freundlich adsorption isotherm equation. The KOC values were 373.69 and 726.86 mL/g, respectively, which revealed higher adsorption capacity of paddy soil than that of the red soil. The degradation half-lives of fenhexamid under the aerobic conditions in the red soil and the paddy soil were 0.63 and 5.06 d, respectively, whereas they were 6.80 and 9.24 d, respectively, under the anaerobic conditions. It was demonstrated that the degradation of fenhexamid was faster under the aerobic condition than that under the anaerobic conditions. Fenhexamid was of low ground water contamination potential and its ground water ubiquity score values were 1.19 and 1.10 in the red soil and the paddy soil, respectively. The results have provided more data for the evaluation of the ecological risk of fenhexamid.

       

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