庄占兴, 路福绥, 郭雯婷, 崔蕊蕊, 范金勇, 刘钰. 分散剂萘磺酸盐甲醛缩合物对氟铃脲悬浮剂流变性的影响[J]. 农药学学报, 2017, 19(1): 100-106. DOI: 10.16801/j.issn.1008-7303.2017.0014
    引用本文: 庄占兴, 路福绥, 郭雯婷, 崔蕊蕊, 范金勇, 刘钰. 分散剂萘磺酸盐甲醛缩合物对氟铃脲悬浮剂流变性的影响[J]. 农药学学报, 2017, 19(1): 100-106. DOI: 10.16801/j.issn.1008-7303.2017.0014
    ZHUANG Zhanxing, LU Fusui, GUO Wenting, CUI Ruirui, FAN Jinyong, LIU Yu. Effects of naphthyl sulfonate formaldehyde condensation dispersant on the rheological properties of hexaflumuron suspension concentrate[J]. Chinese Journal of Pesticide Science, 2017, 19(1): 100-106. DOI: 10.16801/j.issn.1008-7303.2017.0014
    Citation: ZHUANG Zhanxing, LU Fusui, GUO Wenting, CUI Ruirui, FAN Jinyong, LIU Yu. Effects of naphthyl sulfonate formaldehyde condensation dispersant on the rheological properties of hexaflumuron suspension concentrate[J]. Chinese Journal of Pesticide Science, 2017, 19(1): 100-106. DOI: 10.16801/j.issn.1008-7303.2017.0014

    分散剂萘磺酸盐甲醛缩合物对氟铃脲悬浮剂流变性的影响

    Effects of naphthyl sulfonate formaldehyde condensation dispersant on the rheological properties of hexaflumuron suspension concentrate

    • 摘要: 为研究分散剂萘磺酸盐甲醛缩合物(NNO)对氟铃脲悬浮剂流变性的影响,以指导该剂型的加工,采用控制应力流变仪测定了NNO的用量、分子质量及氟铃脲质量分数变化等因素下制剂的流变性。结果发现:以NNO为分散剂制备的氟铃脲悬浮剂的流变曲线符合Herschel-Bulkley流变模型;NNO的分子质量范围和用量会影响氟铃脲悬浮剂的流变性能。在固定NNO质量分数为3%的条件下,当氟铃脲质量分数≥20%时,流动行为指数(n) < 1.0,悬浮体系表现为“剪切变稀”的假塑性流体特征;当氟铃脲的质量分数≤15%时,n>1.0,悬浮体系表现为“剪切增稠”的胀性流体特征。氟铃脲悬浮剂的流变参数屈服值(τH)与NNO和氟铃脲的相对加入量有关。当氟铃脲含量过高时,则NNO不能在氟铃脲颗粒界面形成饱和吸附,裸露的氟铃脲颗粒界面间相互搭接形成结构,因而具有较大的屈服值;当氟铃脲含量过低,则多余的NNO可在悬浮的氟铃脲颗粒间搭接形成结构,也使其屈服值增大。在试验条件下,NNO的分子质量愈大,所制备氟铃脲悬浮剂的表观黏度和屈服值愈小,流动行为指数虽略有增加,但均小于1,仍表现为假塑性特征。本研究结果表明:相同情况下,以萘磺酸盐甲醛缩合物(NNO)为分散剂制备的氟铃脲悬浮剂的屈服值和流动行为指数均高于以苯乙烯丙烯酸无规共聚物(MOTAS)为分散剂制备的氟铃脲悬浮剂。

       

      Abstract: In order to study the effect of naphthyl sulfonate formaldehyde condensation (NNO) on the rheological properties of hexaflumuron suspension concentrate (SC), and to facilitate its processing procedure, the rheology behavior of hexaflumuron SC prepared from with the variation of polymer dispersant NNO of different mass fractions, molecular weights and hexaflumuron mass fractions was studied by using the control stress rheometer. The results demonstrated that the rheological curve of hexaflumuron SC, which include NNO, coincided with the Herschel-Bulkley rheological model. The range of the NNO mass fractions and dosage affected the rheology property of hexaflumuron SC. With 3.0% NNO in mass fractions, the SC was pseudoplastic fluid. The flow behavior index (n) was less than 1.0 when the concentration of hexaflumuron was higher than 20%. The SC was bulging plastic fluid when the flow behavior index was higher than 1.0, while the hexaflumuron mass fractions were less than 15%. The yield value (τH) of hexaflumuron SC was correlated with the relative mass fractions of NNO and hexaflumuron. When the hexaflumuron mass fraction was too high, saturated adsorption was inhibited on the surface of hexaflumuron granule. Therefore the bare hexaflumuron granule surface overlapped with each other and formed structure with higher yield value. When the hexaflumuron mass fractions were moderate, saturated adsorption was achieved on the granule surface. When the hexaflumuron mass fraction was too low, the excess NNO can form a structure between the suspended granules of hexaflumuron and increase the yield value. Under this test conditions, the viscidity and yield value of the hexaflumuron SC decreased with the increase of NNO molecular weight. The flow behavior index was also increased slightly, however, it was still less than 1. The properties of "shear thinning" of the pseudo-plasticity did not change, which indicated that the molecular weight of NNO and its concentration were both influential factors to the hexaflumuron SC rheology. The results showed that the yield value τH and flow behavior index were higher in hexaflumuron SC with dispersant NNO than that with dispersant MOTAS under the same conditions.

       

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