孙效, 吴燕华, 王敏, 边庆花, 钟江春. 草地贪夜蛾性信息素的化学合成与应用研究进展[J]. 农药学学报, 2021, 23(2): 199-208. DOI: 10.16801/j.issn.1008-7303.2021.0042
    引用本文: 孙效, 吴燕华, 王敏, 边庆花, 钟江春. 草地贪夜蛾性信息素的化学合成与应用研究进展[J]. 农药学学报, 2021, 23(2): 199-208. DOI: 10.16801/j.issn.1008-7303.2021.0042
    SUN Xiao, WU Yanhua, WANG Min, BIAN Qinghua, ZHONG Jiangchun. Research progress on chemical synthesis and application of the sex pheromone of Spodoptera frugiperda[J]. Chinese Journal of Pesticide Science, 2021, 23(2): 199-208. DOI: 10.16801/j.issn.1008-7303.2021.0042
    Citation: SUN Xiao, WU Yanhua, WANG Min, BIAN Qinghua, ZHONG Jiangchun. Research progress on chemical synthesis and application of the sex pheromone of Spodoptera frugiperda[J]. Chinese Journal of Pesticide Science, 2021, 23(2): 199-208. DOI: 10.16801/j.issn.1008-7303.2021.0042

    草地贪夜蛾性信息素的化学合成与应用研究进展

    Research progress on chemical synthesis and application of the sex pheromone of Spodoptera frugiperda

    • 摘要: 利用草地贪夜蛾性信息素进行害虫防控,是极具前景的环境友好型防治技术。本文首先从化学角度简述了草地贪夜蛾性信息素的分离、结构鉴定与应用研究进展,指出其化学成分包括单烯酯与二烯酯;然后重点总结了草地贪夜蛾性信息素的化学合成方法,其中构建Z-型双键的方法主要有炔烃催化氢化法、Z型烯烃复分解反应法、Wittig偶联法、Z型烯烃原料法、烯基硼烷法与环辛二烯开环法,构建E-型双键的方法为格氏试剂偶联法、环丙基乙醇开环法与反式烯酸酯法;最后分析了草地贪夜蛾性信息素研究存在的问题并预测了其未来发展方向。

       

      Abstract: Sex pheromone is one of the most promising and environment-friendly strategies to control the fall armyworm moth. In this review, the separation process, structure identification and application of the sex pheromone of Spodoptera frugiperda were summarized. Its compoments comprise monoolefinic esters and diolefinic esters. The chemical synthesis of the sex pherpmone were reviewed. Among them, the construction of the Z- double bond was mainly involved in catalytic hydrogenation of alkyne, Z-selective cross metathesis of olefin, Z-olefin, Wittig coupling, vinylic organoborane and ring opening of cyclooctadiene and the E-one included Grignard coupling, ring opening of cyclepropylethanol and E-olefinic ester. Besides, the current problems and the future researches of the sex pheromone of S. frugiperda were discussed.

       

    /

    返回文章
    返回