叶雪珠, 陈德, 肖文丹, 张棋, 赵首萍. 不同类型农药中重金属分布特征及风险分析[J]. 农药学学报, 2023, 25(1): 227-236. DOI: 10.16801/j.issn.1008-7303.2022.0096
    引用本文: 叶雪珠, 陈德, 肖文丹, 张棋, 赵首萍. 不同类型农药中重金属分布特征及风险分析[J]. 农药学学报, 2023, 25(1): 227-236. DOI: 10.16801/j.issn.1008-7303.2022.0096
    YE Xuezhu, CHEN De, XIAO Wendan, ZHANG Qi, ZHAO Shouping. Distribution characteristics and risk analysis of heavy metals in pesticides[J]. Chinese Journal of Pesticide Science, 2023, 25(1): 227-236. DOI: 10.16801/j.issn.1008-7303.2022.0096
    Citation: YE Xuezhu, CHEN De, XIAO Wendan, ZHANG Qi, ZHAO Shouping. Distribution characteristics and risk analysis of heavy metals in pesticides[J]. Chinese Journal of Pesticide Science, 2023, 25(1): 227-236. DOI: 10.16801/j.issn.1008-7303.2022.0096

    不同类型农药中重金属分布特征及风险分析

    Distribution characteristics and risk analysis of heavy metals in pesticides

    • 摘要: 为探明不同类型农药中重金属分布特征及农药被使用后其中重金属在土壤和蔬菜中的累积风险,从市场采集54个常用农药制剂品种并开展田间试验,研究不同农药制剂中重金属的含量分布及其使用安全风险。结果表明:农药制剂中存在一定量的重金属,其中Cr、As、Cd、Hg和Pb的平均含量分别为21.2、3.23、0.78、0.85和3.43 mg/kg;在非Cu/Zn农药制剂中,Cu和Zn的平均含量分别为9.22 和18.1 mg/kg;每种农药中检出重金属元素在3~7种;在Cu制剂中有较高含量的Zn,而在Zn制剂中伴随有较高含量的Cu和Cd。农药制剂中Zn-Cd、Cr-Pb-As、Hg-As的含量显著相关,来源具有同源性。在农药使用当年,土壤中重金属含量增加约5.74 × 10−8~5.46 × 10−5 mg/kg,其中施用杀虫剂后Cr、As、Hg及施用杀菌剂后Cu、Zn、Cd在土壤中的增量相对高于施用其他类型农药,但相比中国国家标准 GB15618 2018《土壤环境质量 农用地土壤污染风险管控标准(试行)》,由农药使用带来的土壤中重金属的年累积量可忽略不计;相比未喷施农药的对照,施用噻森铜5次,可使白菜中的Pb含量显著增加,施用丙森锌3次和5次均可使白菜中的Cd含量显著增加,但Cd、Pb均未超过国家标准限量值,最高含量约为限量值的20%和10%,风险较低。

       

      Abstract: In order to find out the distribution characteristics of heavy metals in pesticides and the cumulative risk of heavy metals in soil and vegetables after pesticide application, 54 commonly used pesticide formulations were collected from the market, and the field experiments were conducted to investigate the contents of heavy metals in different pesticide formulations and their safety risks after application. The results showed that heavy metal was common in pesticide formulations, and the average contents of Cr, As, Cd, Hg and Pb were 21.2, 3.23, 0.78, 0.85 and 3.43 mg/kg, respectively. The average contents of Cu and Zn in non Cu/Zn pesticides were 9.22 and 18.1 mg/kg, respectively. Three to seven heavy metals were detected in each pesticide. Relatively high content of Zn was detected in pesticide formulations containing Cu, while high contents of Cu and Cd were detected in Zn-containing pesticides. The results of correlation analysis showed that the contents of Zn-Cd, Cr-Pb-As and Hg-As in pesticide formulations were significantly correlated and their sources were homologous. In the year of pesticide use, the contents of heavy metals in soil increased by 5.74 × 10−8 mg/kg to 5.46 × 10−5 mg/kg. Compared to the application of other types of pesticides, the increment of Cr, As and Hg in soil was significantly higher after the application of insecticides, and the increment of Cu, Zn and Cd in soil was significantly higher after the application of fungicides. Nevertheless, according to the soil environmental quality standard in the National Standard of China (GB15618—2018), the annual accumulation of heavy metals in soil caused by pesticides application was negligible. In comparison with the blank control that no pesticide was sprayed, the application of thiosen copper for 5 times significantly increased the content of Pb in cabbage, and the application of propineb for 3 and 5 times significantly increased the content of Cd in cabbage, but neither Cd nor Pb exceeded the national limit. The maximum contents of Cd and Pb in cabbage were about 20% and 10% of the national limit value, respectively, suggesting that the risk was low.

       

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