环庚草醚在4种土壤中的消解、吸附和迁移特性

    Dissipation, adsorption, and transport of cinmethylin in four types of soil

    • 摘要: 以潮土、褐土、黑土和红壤土4种作物种植代表性地区土壤为研究对象,采用振荡平衡和土壤薄层层析法系统研究了环庚草醚在土壤中的消解、吸附和迁移行为。结果表明,环庚草醚在4种土壤中的消解均遵循一级动力学方程,半衰期在47.2 ~ 443.2 d之间,其中厌氧微生物、有机质含量和土壤pH值是调控环庚草醚消解的重要因素。采用Elovich模型和Freundlich模型拟合环庚草醚的吸附和等温吸附的数据,决定系数(R2)均在0.979以上。环庚草醚在土壤中的Freundlich吸附强度的吸附常数(KF)在0.30 ~ 3.76 (mg1–n/(L·mg))之间。红壤土和褐土的迁移率因子(Rf)在0.10 ~ 0.35之间,潮土和黑土的Rf在0.35 ~ 0.65之间,表明环庚草醚在4种土壤中的迁移介于不易移动到中等移动之间。综上所述,环庚草醚在4种土壤中均为中等消解农药,在红壤土和褐土中吸附亲和力较高,不易移动;而在潮土和黑土中吸附亲和力低,移动性中等,对地下水系统的污染隐患较大。

       

      Abstract: To study the dissipation, adsorption, and mobility characteristics of cinmethylin in soil, the soils from four representative crop-cultivation regions, characterized by fluvo-aquic soil, brown soil, black soil, and red loam, were selected for investigation. The dissipation, adsorption and mobility behaviors of cinmethylin in soils were systematically investigated by using shock equilibrium and soil thin-layer chromatography. The results showed that the dissipation of cinmethylin in four soil types followed a first-order kinetic equation, with half-lives ranging from 47.2 to 443.2 d, in which anaerobic microorganisms, organic matter content, and soil pH value were the most important factors regulating the dissipation of cinmethylin. The Elovich and Freundlich models were used to fit the data for adsorption and isothermal adsorption of cinmethylin, and the R2 values were above 0.979. The Freundlich adsorption coefficients of cinmethylin in soils ranged from 0.30 to 3.76 (mg1–n/(L·mg)). Rf ranged from 0.10 to 0.35 for red loam and brown soils and from 0.35 to 0.65 for fluvo-aquic soil and black soils, indicated that the mobility of cinmethylin in the four soils ranged from weak to moderately mobile. In summary, cinmethylin is a medium dissipation pesticide in all four soils, with highly adsorption and weak mobility in red loam and brown soils; in contrast, cinmethylin is weak adsorbed, moderate mobility, and the potential for contamination of groundwater systems is high in fluvo–aquic soil and black soil.

       

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