生物炭的改性及其对农药的吸附机理研究进展

    Progress of research on the modification of biochar and its adsorption mechanism of pesticides

    • 摘要: 农药污染问题日益突出,当农药施用剂量持续高于其安全使用标准、或在农业生产中大范围推广应用时,会对生物体造成一定的毒性影响,并导致土壤和水体污染。生物炭具有高比表面积、高孔容积和表面含有丰富的官能团等特点,可以用于吸附残留农药,具有低成本、高效率等优势,且改性能够提高生物炭对农药的吸附能力。本文系统综述了生物炭的制备、特性及形成机制,重点阐述了生物炭化学、物理及生物改性的机制及其分别在农药吸附方面的研究进展,总结了改性生物炭对农药吸附作用的机制,并对生物炭在农药吸附上的研究做出展望,为优化生物炭性能、减少农药污染提供理论依据。

       

      Abstract: The problem of pesticide pollution is becoming increasingly prominent. When pesticides are used in excess of safe usage standards or is widely promoted in agricultural production, they can have toxic effects on organisms and lead to soil and water pollution. Therefore, there is an urgent need for economical and effective raw materials or technologies to reduce the negative impact of pesticides. Biochar has a the characteristics of high specific surface area and pore volume, as well as abundant functional groups on the surface, which can be used for adsorbing pesticides. It is also low-cost and highly efficient. The adsorption capacity of biochar for pesticides is limited, but this can be improved through modification. This paper systematically reviewed the preparation, characteristics, and formation mechanisms of biochar, with a focus on the mechanisms of chemical modification, physical modification, and biological modification of biochar, as well as their research progress in pesticide adsorption. The mechanisms of modified biochar on pesticide adsorption were summarized, and the research prospects of biochar on pesticide adsorption were discussed. This work provides a theoretical basis for optimizing the performance of biochar and reducing pesticide pollution.

       

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