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草地贪夜蛾性信息素的化学合成与应用研究进展

孙效 吴燕华 王敏 边庆花 钟江春

孙效, 吴燕华, 王敏, 边庆花, 钟江春. 草地贪夜蛾性信息素的化学合成与应用研究进展[J]. 农药学学报, 2021, 23(2): 199-208. doi: 10.16801/j.issn.1008-7303.2021.0042
引用本文: 孙效, 吴燕华, 王敏, 边庆花, 钟江春. 草地贪夜蛾性信息素的化学合成与应用研究进展[J]. 农药学学报, 2021, 23(2): 199-208. doi: 10.16801/j.issn.1008-7303.2021.0042
Xiao SUN, Yanhua WU, Min WANG, Qinghua BIAN, Jiangchun ZHONG. Research progress on chemical synthesis and application of the sex pheromone of Spodoptera frugiperda[J]. Chinese Journal of Pesticide Science, 2021, 23(2): 199-208. doi: 10.16801/j.issn.1008-7303.2021.0042
Citation: Xiao SUN, Yanhua WU, Min WANG, Qinghua BIAN, Jiangchun ZHONG. Research progress on chemical synthesis and application of the sex pheromone of Spodoptera frugiperda[J]. Chinese Journal of Pesticide Science, 2021, 23(2): 199-208. doi: 10.16801/j.issn.1008-7303.2021.0042

草地贪夜蛾性信息素的化学合成与应用研究进展

doi: 10.16801/j.issn.1008-7303.2021.0042
基金项目: 国家重点研发计划 (No. 2017YFD0201404)
详细信息
    作者简介:

    孙效,男,硕士研究生,E­mail:595660272@qq.com

    通讯作者:

    钟江春,通信作者 (Author for correspondence),男,副教授,研究方向为农药合成与不对称合成,E­mail:zhong@cau.edu.cn

  • 中图分类号: S482.38; O623.6; TQ459

Research progress on chemical synthesis and application of the sex pheromone of Spodoptera frugiperda

  • 摘要: 利用草地贪夜蛾性信息素进行害虫防控,是极具前景的环境友好型防治技术。本文首先从化学角度简述了草地贪夜蛾性信息素的分离、结构鉴定与应用研究进展,指出其化学成分包括单烯酯与二烯酯;然后重点总结了草地贪夜蛾性信息素的化学合成方法,其中构建Z-型双键的方法主要有炔烃催化氢化法、Z型烯烃复分解反应法、Wittig偶联法、Z型烯烃原料法、烯基硼烷法与环辛二烯开环法,构建E-型双键的方法为格氏试剂偶联法、环丙基乙醇开环法与反式烯酸酯法;最后分析了草地贪夜蛾性信息素研究存在的问题并预测了其未来发展方向。
  • 图  1  草地贪夜蛾性信息素活性成分

    Figure  1.  The active components in the sex pheromone of Spodoptera frugiperda

    1  炔烃催化氢化法合成性信息素1

    1.  Synthesis of the sex pheromone 1 using the catalytic hydrogenation of alkyne

    2  炔烃催化氢化法合成性信息素2

    2.  Synthesis of the sex pheromone 2 using the catalytic hydrogenation of alkyne

    3  炔烃催化氢化法合成性信息素3

    3.  Synthesis of the sex pheromone 3 using the catalytic hydrogenation of alkyne

    4  炔烃催化氢化法合成性信息素4

    4.  Synthesis of the sex pheromone 4 using the catalytic hydrogenation of alkyne

    5  Z-型烯烃复分解反应法合成性信息素2

    5.  Synthesis of the sex pheromone 2 using the Z-selective cross metathesis of olefin

    6  Wittig偶联法合成性信息素4

    6.  Synthesis of the sex pheromone 4 using the Wittig coupling

    7  Z-型烯烃原料法合成性信息素1

    7.  Synthesis of the sex pheromone 1 from Z-olefin

    8  Z-型烯烃原料法合成性信息素3

    8.  Synthesis of the sex pheromone 3 from Z-olefin

    9  烯基硼烷法合成性信息素4

    9.  Synthesis of the sex pheromone 4 using vinylic organoborane

    10  1,5-环辛二烯法合成性信息素4

    10.  Synthesis of the sex pheromone 4 from 1,5-cyclooctadiene

    11  1-甲基-1,5-环辛二烯法合成性信息素4

    11.  Synthesis of the sex pheromone 4 from 1-methyl-1,5-cyclooctadiene

    12  格氏试剂偶联法合成性信息素5

    12.  Synthesis of the sex pheromone 5 using Grignard coupling

    13  环丙基乙醇开环法合成性信息素6

    13.  Synthesis of the sex pheromone 6 from 1-cyclepropylethanol

    14  (E)-3-戊烯酸甲酯法合成性信息素6

    14.  Synthesis of the sex pheromone 6 from (E)-pent-3-enoic acid methyl ester

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  • 收稿日期:  2020-10-17
  • 录用日期:  2020-11-22
  • 刊出日期:  2021-04-10

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