张斌, 曹立冬, 刘峰, 黄啟良, 张鹏, 陈澄宇. 几种新型润湿分散剂在悬浮剂加工中的应用评价[J]. 农药学学报, 2014, 16(2): 197-205. DOI: 10.3969/j.issn.1008-7303.2014.02.14
    引用本文: 张斌, 曹立冬, 刘峰, 黄啟良, 张鹏, 陈澄宇. 几种新型润湿分散剂在悬浮剂加工中的应用评价[J]. 农药学学报, 2014, 16(2): 197-205. DOI: 10.3969/j.issn.1008-7303.2014.02.14
    ZHANG Bin, CAO Lidong, LIU Feng, HUANG Qiliang, ZHANG Peng, CHEN Chengyu. Evaluation of the application performance of several domestic surfactants in suspension concentrate[J]. Chinese Journal of Pesticide Science, 2014, 16(2): 197-205. DOI: 10.3969/j.issn.1008-7303.2014.02.14
    Citation: ZHANG Bin, CAO Lidong, LIU Feng, HUANG Qiliang, ZHANG Peng, CHEN Chengyu. Evaluation of the application performance of several domestic surfactants in suspension concentrate[J]. Chinese Journal of Pesticide Science, 2014, 16(2): 197-205. DOI: 10.3969/j.issn.1008-7303.2014.02.14

    几种新型润湿分散剂在悬浮剂加工中的应用评价

    Evaluation of the application performance of several domestic surfactants in suspension concentrate

    • 摘要: 为快速表征新型表面活性剂在农药剂型加工中的主要功能,本研究通过测定几类国产高分子表面活性剂的临界胶束浓度及该浓度下的表面张力和润湿时间等性能,初步判断其适合作润湿剂还是分散剂;运用流点法确定了各助剂在多菌灵悬浮剂中的用量及配比;利用不同助剂类型及不同用量加工了多种50%多菌灵悬浮剂,并测定了其性能。结果表明:将润湿剂和分散剂按不同比例混合后,通过测定其流点来确定悬浮剂中助剂用量的方法是可行的;从对各制剂的性能测试结果可以看出,不管是用流点用量还是5倍流点用量,所选助剂多数可成功加工出合格试样。将性能较好的制剂按照农药登记推荐使用浓度稀释1 000倍后,测定其表面张力及在小麦叶片上的接触角和持液量,推断其田间使用情况。结果显示:药液因表面张力过大未能润湿小麦叶片,国产助剂与国外助剂差别不显著,甚至部分国产助剂的性能还优于国外助剂的;制备悬浮剂时将磺酸盐类与聚羧酸盐类分散剂配合使用效果较好。

       

      Abstract: In order to evaluate the application performance of some domestic polymeric surfactants in pesticide formulations processing, the surface properties including critical micelle concentration (CMC), surface tension and wetting time and etc were investigated. Based on these performance parameters determined, preliminary estimation on whether the surfactants were suited for wetting agents or dispersants was made. The dosage and ratio of various additives in carbendazim suspension concentrate (SC) was determined using flow point method. Then processing and validation test on carbendazim 500SC with different contents of surfactants was examined.The results showed that determination of the additives contents in SC through flow point assay of the mixture of wetting agent and dispersant solution mixed proportionally is completely feasible. Both dosage of flow point and 5 times dosage can process qualified samples successfully. According to the recommended concentration of pesticide registration, dilute the formulation by 1 000 times and determine its liquid surface tension, contact angle of the wheat leaf and liquid holdup of the formulation to direct the field application. The results showed that liquid surface tension is too large to wet wheat leaves. It was indicated that the performance of samples prepared with both domestic and oversea additives had no obvious differences. Several domestic additives showed better performance than oversea counterparts. Application of polysulfonate and polycarboxylate surfactants cooperatively represented superiority in the preparation of suspension concentrate.

       

    /

    返回文章
    返回