Abstract: After 3-aminomethyl or 2-chloride-5-aminomethyl pyridine reacted with 2-cyano-3,3-dimethylthio ethyl acrylate the simple fatty amines were added to the reactant. The intermediates were not separated to yield seven novel compounds. All the structures of new compounds were confirmed by elemental analysis and H1 NMR. The configurations of the compounds were discussed in contrast with the 1H NMR of the intermediates.