吴珉, 胡秀卿, 赵华, 朱亚红, 徐浩平立凤, 王新全, 李振. 作物和土壤中乙酰甲胺磷及其代谢物甲胺磷消解研究[J]. 农药学学报, 2009, 11(1): 114-120.
    引用本文: 吴珉, 胡秀卿, 赵华, 朱亚红, 徐浩平立凤, 王新全, 李振. 作物和土壤中乙酰甲胺磷及其代谢物甲胺磷消解研究[J]. 农药学学报, 2009, 11(1): 114-120.
    WU Min, HU Xiou-qing, ZHAO Hua, ZHU Ya-hong, XU HaoPING Li-feng, WANG Xin-quan, LI Zhen. Field Residue Decline Study of Acephate andMethamidophos in Crop and Soil[J]. Chinese Journal of Pesticide Science, 2009, 11(1): 114-120.
    Citation: WU Min, HU Xiou-qing, ZHAO Hua, ZHU Ya-hong, XU HaoPING Li-feng, WANG Xin-quan, LI Zhen. Field Residue Decline Study of Acephate andMethamidophos in Crop and Soil[J]. Chinese Journal of Pesticide Science, 2009, 11(1): 114-120.

    作物和土壤中乙酰甲胺磷及其代谢物甲胺磷消解研究

    Field Residue Decline Study of Acephate andMethamidophos in Crop and Soil

    • 摘要: 为评价乙酰甲胺磷在作物上使用的安全性,采用气相色谱法研究了不同气候条件(亚热带和暖温带)下的4种作物(甘蓝、萝卜、水稻、柑桔)和8个土壤样品(4种作物各自在两个试验地点的土壤)中乙酰甲胺磷及其代谢物甲胺磷的消解情况。结果表明:乙酰甲胺磷在作物和土壤中均可代谢产生甲胺磷,作物中的2 h甲胺磷代谢产率主要由作物种类决定。作物中乙酰甲胺磷的消解半衰期为3.1~13.5 d,甲胺磷为2.7~12.8 d;土壤中乙酰甲胺磷的半衰期为1.4~6.4 d,甲胺磷为4.5~10.7 d。土壤pH值对乙酰甲胺磷的消解影响显著,其在碱性土壤中消解较快。具有较高净辐射的气候条件会促进乙酰甲胺磷及甲胺磷在作物中的消解,因此种植在暖温带气候条件下的作物上使用乙酰甲胺磷较种植在亚热带气候条件下的具有更高的甲胺磷残留风险。乙酰甲胺磷施用在叶菜类蔬菜上可能会有较高的甲胺磷残留风险,建议叶菜类蔬菜应谨慎使用乙酰甲胺磷。

       

      Abstract: In order to evaluate the safety application of acephate,field residue decline study of acephate in different climatic conditions of crop and soil were studied using gas chromatography(GC) determination method.The results showed that acephate could metabolize to methamidophos rapidly in tested crop and soil.Metabolic rate of methamidophos in 2 hours was significantly affected by crop species.The half-life of acephate was 3.1~13.5 days in crop,while that of its metabolite methamidophos was 2.7~12.8 days in crop.The half-life of acephate was 1.4~6.4 days in soil,and that of methamidophos was 4.5~10.7 days in soil.The degradation of acephate and methamidophos in soil was affected significantly by soil pH,the alkaline soil caused faster degradation.The climate condition of higher net radiation may accelerate the degradation of acephate and methamidophos in crop,so the crop applied acephate had higher methamidophos residue risk in the warm climate condition than in the subtropical climate condition.Leafy vegetables applied acephate have higher methamidophos residue risk than other crops,it's suggested that leafy vegetables needed to use acephate carefully.

       

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